Praseodymium oxyiodide
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| Other names
Praseodymium oxide iodide
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3D model (JSmol)
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| Properties | |
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| Molar mass | 283.811 g·mol−1 |
| Density | 5.46 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Praseodymium oxyiodide also (praseodymium oxide iodide) is an inorganic compound of praseodymium, oxygen, and iodine with the chemical formula PrOI.[1][2]
Synthesis
PrOI can be synthesized by reacting praseodymium triiodide (PrI3) with oxygen at a controlled partial pressure.
Alternatively, PrOI can form as a decomposition product of praseodymium diiodide PrI2 in the presence of moisture, or through the reaction of PrI3 with praseodymium oxide (Pr2O3).[3]
- 2 PrI2 + 2 H2O → 2 PrOI + H2↑ + 2 HI
References
- ^ Potapova, O. G.; Vasil'eva, I. G.; Borisov, S. V. (1 May 1977). "Crystal structure of praseodymium oxide iodide". Journal of Structural Chemistry. 18 (3): 459–462. Bibcode:1977JStCh..18..459P. doi:10.1007/BF00753092. ISSN 1573-8779. Retrieved 4 July 2025.
- ^ Heiniö, Outi; Leskelä, Markku; Niinistö, Lauri; Tuhtar, Dinko; Sjöblom, Johan; Strand, T. G.; Sukhoverkhov, V. F. (1980). "Structural and Thermal Properties of Rare Earth Triiodide Hydrates". Acta Chemica Scandinavica. 34a: 207–211. doi:10.3891/acta.chem.scand.34a-0207. ISSN 0904-213X.
- ^ hrsg. von Georg Brauer. Unter Mitarb. von M. Baudler (1975). Handbuch der präparativen anorganischen Chemie / 1 (in German). Stuttgart: Enke. p. 1081. ISBN 3-432-02328-6. OCLC 310719485.