Deuterated DMF

Deuterated DMF
Names
IUPAC name
1-Deuterio-N,N-bis(trideuteriomethyl)formamide
Other names
  • Dimethylformamide-d7
  • N,N-Dimethylformamide-d7
  • Heptadeutero-N,N-dimethylformamide
Identifiers
3D model (JSmol)
Abbreviations DMF-d7
1908468
ChemSpider
ECHA InfoCard 100.022.497
EC Number
  • 224-745-8
UN number 2265
  • InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D N
    Key: ZMXDDKWLCZADIW-YYWVXINBSA-N N
  • [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]
Properties
C
32
H
7NO or C
3D
7NO
Molar mass 80.1369 g mol−1
Appearance Colourless liquid
Density 1.03 g mL−1
Boiling point 153 °C (307 °F; 426 K)
1.428
Hazards
GHS labelling:
Danger
H312, H319, H332, H360
P280, P305+P351+P338, P308+P313
Flash point 58 °C (136 °F; 331 K)
Explosive limits 2.2–15.2%
Lethal dose or concentration (LD, LC):
  • 2.8 g kg−1 (oral, rat)
  • 1.5–4.72 g kg−1 (dermal, rabbit)
Related compounds
Related alkanamides
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.[1][2]

References

  1. ^ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation". Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297.
  2. ^ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution". New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. S2CID 132588760.


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